19F NMR studies of 3M ionomer adsorption on carbon supports and Pt/C catalysts

N. M. Cantillo; L. Li; J. Peng; G. A. Goenaga; T. A. Zawodzinski

doi:10.1149/08008.0259ecst

¹⁹F NMR studies of 3M ionomer adsorption on carbon supports and Pt/C catalysts

N. M. Cantillo
, L. Li
, J. Peng
, G. A. Goenaga
, T. A. Zawodzinski

Producción científica: Capítulo en Libro/Informe › Contribución a la conferencia

1 Cita (Scopus)

Resumen

In this study, the interactions between 3M 825 equivalent-weight (EW) ionomer and carbon support or carbon-supported platinum (Pt/C) catalyst particles were studied. The support and catalyst materials (with and without ionomer addition) were analyzed with Brunauer-Emmet-Teller (BET) nitrogen adsorption-desorption. 3M ionomer/carbon/Pt interactions were also explored through differential scanning calorimetry (DSC). Progress toward developing methods for studying polymer adsorption onto supports using ¹⁹F Nuclear Magnetic Resonance Spectroscopy (NMR) is also reported. Using these methods, a series of ionomer solutions were analyzed to explore the different interactions between components (Pt/Carbon, and Carbon/ionomer).

Idioma original	Inglés estadounidense
Título de la publicación alojada	ECS Transactions
Editores	D. J. Jones, F. Buechi, K. E. Swider-Lyons, P. N. Pintauro, H. Uchida, T. J. Schmidt, B. S. Pivovar, H. A. Gasteiger, A. Z. Weber, P. A. Shirvanian, J. M. Fenton, T. F. Fuller, K. Shinohara, K. A. Perry, P. Strasser, C. Coutanceau, S. Mitsushima, R. A. Mantz, S. Narayan, V. Ramani, K. E. Ayers, Y.-T. Kim, H. Xu
Editorial	Electrochemical Society Inc.
Páginas	259-268
Número de páginas	10
Edición	8
ISBN (versión digital)	9781607688259
ISBN (versión impresa)	9781623324773
DOI	https://doi.org/10.1149/08008.0259ecst
Estado	Publicada - 2017
Publicado de forma externa	Sí
Evento	Symposium on Polymer Electrolyte Fuel Cells 17, PEFC 2017 - 232nd ECS Meeting - National Harbor, Estados Unidos Duración: oct 1 2017 → oct 5 2017

Serie de la publicación

Nombre	ECS Transactions
Número	8
Volumen	80
ISSN (versión impresa)	1938-6737
ISSN (versión digital)	1938-5862

Conferencia

Conferencia	Symposium on Polymer Electrolyte Fuel Cells 17, PEFC 2017 - 232nd ECS Meeting
País/Territorio	Estados Unidos
Ciudad	National Harbor
Período	10/1/17 → 10/5/17

ODS de las Naciones Unidas

Este resultado contribuye a los siguientes Objetivos de Desarrollo Sostenible

ODS 1: Fin de la pobreza

Áreas temáticas de ASJC Scopus

Ingeniería General

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10.1149/08008.0259ecst

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Cantillo, N. M., Li, L., Peng, J., Goenaga, G. A., & Zawodzinski, T. A. (2017). ¹⁹F NMR studies of 3M ionomer adsorption on carbon supports and Pt/C catalysts. En D. J. Jones, F. Buechi, K. E. Swider-Lyons, P. N. Pintauro, H. Uchida, T. J. Schmidt, B. S. Pivovar, H. A. Gasteiger, A. Z. Weber, P. A. Shirvanian, J. M. Fenton, T. F. Fuller, K. Shinohara, K. A. Perry, P. Strasser, C. Coutanceau, S. Mitsushima, R. A. Mantz, S. Narayan, V. Ramani, K. E. Ayers, Y.-T. Kim, ... H. Xu (Eds.), ECS Transactions (8 ed., pp. 259-268). (ECS Transactions; Vol. 80, N.º 8). Electrochemical Society Inc.. https://doi.org/10.1149/08008.0259ecst

Cantillo, N. M. ; Li, L. ; Peng, J. et al. / ¹⁹F NMR studies of 3M ionomer adsorption on carbon supports and Pt/C catalysts. ECS Transactions. editor / D. J. Jones ; F. Buechi ; K. E. Swider-Lyons ; P. N. Pintauro ; H. Uchida ; T. J. Schmidt ; B. S. Pivovar ; H. A. Gasteiger ; A. Z. Weber ; P. A. Shirvanian ; J. M. Fenton ; T. F. Fuller ; K. Shinohara ; K. A. Perry ; P. Strasser ; C. Coutanceau ; S. Mitsushima ; R. A. Mantz ; S. Narayan ; V. Ramani ; K. E. Ayers ; Y.-T. Kim ; H. Xu. 8. ed. Electrochemical Society Inc., 2017. pp. 259-268 (ECS Transactions; 8).

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title = "19F NMR studies of 3M ionomer adsorption on carbon supports and Pt/C catalysts",

abstract = "In this study, the interactions between 3M 825 equivalent-weight (EW) ionomer and carbon support or carbon-supported platinum (Pt/C) catalyst particles were studied. The support and catalyst materials (with and without ionomer addition) were analyzed with Brunauer-Emmet-Teller (BET) nitrogen adsorption-desorption. 3M ionomer/carbon/Pt interactions were also explored through differential scanning calorimetry (DSC). Progress toward developing methods for studying polymer adsorption onto supports using 19F Nuclear Magnetic Resonance Spectroscopy (NMR) is also reported. Using these methods, a series of ionomer solutions were analyzed to explore the different interactions between components (Pt/Carbon, and Carbon/ionomer).",

author = "Cantillo, \{N. M.\} and L. Li and J. Peng and Goenaga, \{G. A.\} and Zawodzinski, \{T. A.\}",

note = "Funding Information: NMC gratefully acknowledges the support from a Fulbright Fellowship and from the Office of Naval Research under grant N00014-16-1-2095. Research supported at ORNL by the Fuel Cell Technologies Office, Office of Energy Efficiency and Renewable Energy, U.S. Department of Energy. We would also like to thank 3M for providing the ionomer solution. Publisher Copyright: {\textcopyright} The Electrochemical Society.; Symposium on Polymer Electrolyte Fuel Cells 17, PEFC 2017 - 232nd ECS Meeting ; Conference date: 01-10-2017 Through 05-10-2017",

year = "2017",

doi = "10.1149/08008.0259ecst",

language = "English (US)",

isbn = "9781623324773",

series = "ECS Transactions",

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number = "8",

pages = "259--268",

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Cantillo, NM, Li, L, Peng, J, Goenaga, GA & Zawodzinski, TA 2017, ¹⁹F NMR studies of 3M ionomer adsorption on carbon supports and Pt/C catalysts. En DJ Jones, F Buechi, KE Swider-Lyons, PN Pintauro, H Uchida, TJ Schmidt, BS Pivovar, HA Gasteiger, AZ Weber, PA Shirvanian, JM Fenton, TF Fuller, K Shinohara, KA Perry, P Strasser, C Coutanceau, S Mitsushima, RA Mantz, S Narayan, V Ramani, KE Ayers, Y-T Kim & H Xu (eds.), ECS Transactions. 8 ed., ECS Transactions, n.º 8, vol. 80, Electrochemical Society Inc., pp. 259-268, Symposium on Polymer Electrolyte Fuel Cells 17, PEFC 2017 - 232nd ECS Meeting, National Harbor, Estados Unidos, 10/1/17. https://doi.org/10.1149/08008.0259ecst

¹⁹F NMR studies of 3M ionomer adsorption on carbon supports and Pt/C catalysts. / Cantillo, N. M.; Li, L.; Peng, J. et al.
ECS Transactions. ed. / D. J. Jones; F. Buechi; K. E. Swider-Lyons; P. N. Pintauro; H. Uchida; T. J. Schmidt; B. S. Pivovar; H. A. Gasteiger; A. Z. Weber; P. A. Shirvanian; J. M. Fenton; T. F. Fuller; K. Shinohara; K. A. Perry; P. Strasser; C. Coutanceau; S. Mitsushima; R. A. Mantz; S. Narayan; V. Ramani; K. E. Ayers; Y.-T. Kim; H. Xu. 8. ed. Electrochemical Society Inc., 2017. p. 259-268 (ECS Transactions; Vol. 80, N.º 8).

Producción científica: Capítulo en Libro/Informe › Contribución a la conferencia

TY - GEN

T1 - 19F NMR studies of 3M ionomer adsorption on carbon supports and Pt/C catalysts

AU - Cantillo, N. M.

AU - Li, L.

AU - Peng, J.

AU - Goenaga, G. A.

AU - Zawodzinski, T. A.

N1 - Funding Information: NMC gratefully acknowledges the support from a Fulbright Fellowship and from the Office of Naval Research under grant N00014-16-1-2095. Research supported at ORNL by the Fuel Cell Technologies Office, Office of Energy Efficiency and Renewable Energy, U.S. Department of Energy. We would also like to thank 3M for providing the ionomer solution. Publisher Copyright: © The Electrochemical Society.

PY - 2017

Y1 - 2017

N2 - In this study, the interactions between 3M 825 equivalent-weight (EW) ionomer and carbon support or carbon-supported platinum (Pt/C) catalyst particles were studied. The support and catalyst materials (with and without ionomer addition) were analyzed with Brunauer-Emmet-Teller (BET) nitrogen adsorption-desorption. 3M ionomer/carbon/Pt interactions were also explored through differential scanning calorimetry (DSC). Progress toward developing methods for studying polymer adsorption onto supports using 19F Nuclear Magnetic Resonance Spectroscopy (NMR) is also reported. Using these methods, a series of ionomer solutions were analyzed to explore the different interactions between components (Pt/Carbon, and Carbon/ionomer).

AB - In this study, the interactions between 3M 825 equivalent-weight (EW) ionomer and carbon support or carbon-supported platinum (Pt/C) catalyst particles were studied. The support and catalyst materials (with and without ionomer addition) were analyzed with Brunauer-Emmet-Teller (BET) nitrogen adsorption-desorption. 3M ionomer/carbon/Pt interactions were also explored through differential scanning calorimetry (DSC). Progress toward developing methods for studying polymer adsorption onto supports using 19F Nuclear Magnetic Resonance Spectroscopy (NMR) is also reported. Using these methods, a series of ionomer solutions were analyzed to explore the different interactions between components (Pt/Carbon, and Carbon/ionomer).

UR - https://www.scopus.com/pages/publications/85050032179

UR - https://www.scopus.com/pages/publications/85050032179#tab=citedBy

U2 - 10.1149/08008.0259ecst

DO - 10.1149/08008.0259ecst

M3 - Conference contribution

AN - SCOPUS:85050032179

SN - 9781623324773

T3 - ECS Transactions

SP - 259

EP - 268

BT - ECS Transactions

A2 - Jones, D. J.

A2 - Buechi, F.

A2 - Swider-Lyons, K. E.

A2 - Pintauro, P. N.

A2 - Uchida, H.

A2 - Schmidt, T. J.

A2 - Pivovar, B. S.

A2 - Gasteiger, H. A.

A2 - Weber, A. Z.

A2 - Shirvanian, P. A.

A2 - Fenton, J. M.

A2 - Fuller, T. F.

A2 - Shinohara, K.

A2 - Perry, K. A.

A2 - Strasser, P.

A2 - Coutanceau, C.

A2 - Mitsushima, S.

A2 - Mantz, R. A.

A2 - Narayan, S.

A2 - Ramani, V.

A2 - Ayers, K. E.

A2 - Kim, Y.-T.

A2 - Xu, H.

PB - Electrochemical Society Inc.

T2 - Symposium on Polymer Electrolyte Fuel Cells 17, PEFC 2017 - 232nd ECS Meeting

Y2 - 1 October 2017 through 5 October 2017

ER -

Cantillo NM, Li L, Peng J, Goenaga GA, Zawodzinski TA. ¹⁹F NMR studies of 3M ionomer adsorption on carbon supports and Pt/C catalysts. En Jones DJ, Buechi F, Swider-Lyons KE, Pintauro PN, Uchida H, Schmidt TJ, Pivovar BS, Gasteiger HA, Weber AZ, Shirvanian PA, Fenton JM, Fuller TF, Shinohara K, Perry KA, Strasser P, Coutanceau C, Mitsushima S, Mantz RA, Narayan S, Ramani V, Ayers KE, Kim YT, Xu H, editores, ECS Transactions. 8 ed. Electrochemical Society Inc. 2017. p. 259-268. (ECS Transactions; 8). doi: 10.1149/08008.0259ecst