19F NMR studies of 3M ionomer adsorption on carbon supports and Pt/C catalysts

N. M. Cantillo; L. Li; J. Peng; G. A. Goenaga; T. A. Zawodzinski

doi:10.1149/08008.0259ecst

¹⁹F NMR studies of 3M ionomer adsorption on carbon supports and Pt/C catalysts

N. M. Cantillo, L. Li, J. Peng, G. A. Goenaga, T. A. Zawodzinski

Research output: Chapter in Book/Inform › Conference contribution

Abstract

In this study, the interactions between 3M 825 equivalent-weight (EW) ionomer and carbon support or carbon-supported platinum (Pt/C) catalyst particles were studied. The support and catalyst materials (with and without ionomer addition) were analyzed with Brunauer-Emmet-Teller (BET) nitrogen adsorption-desorption. 3M ionomer/carbon/Pt interactions were also explored through differential scanning calorimetry (DSC). Progress toward developing methods for studying polymer adsorption onto supports using ¹⁹F Nuclear Magnetic Resonance Spectroscopy (NMR) is also reported. Using these methods, a series of ionomer solutions were analyzed to explore the different interactions between components (Pt/Carbon, and Carbon/ionomer).

Original language	English (US)
Title of host publication	ECS Transactions
Editors	D. J. Jones, F. Buechi, K. E. Swider-Lyons, P. N. Pintauro, H. Uchida, T. J. Schmidt, B. S. Pivovar, H. A. Gasteiger, A. Z. Weber, P. A. Shirvanian, J. M. Fenton, T. F. Fuller, K. Shinohara, K. A. Perry, P. Strasser, C. Coutanceau, S. Mitsushima, R. A. Mantz, S. Narayan, V. Ramani, K. E. Ayers, Y.-T. Kim, H. Xu
Publisher	Electrochemical Society Inc.
Pages	259-268
Number of pages	10
Edition	8
ISBN (Electronic)	9781607688259
ISBN (Print)	9781623324773
DOIs	https://doi.org/10.1149/08008.0259ecst
State	Published - 2017
Externally published	Yes
Event	Symposium on Polymer Electrolyte Fuel Cells 17, PEFC 2017 - 232nd ECS Meeting - National Harbor, United States Duration: Oct 1 2017 → Oct 5 2017

Publication series

Name	ECS Transactions
Number	8
Volume	80
ISSN (Print)	1938-6737
ISSN (Electronic)	1938-5862

Conference

Conference	Symposium on Polymer Electrolyte Fuel Cells 17, PEFC 2017 - 232nd ECS Meeting
Country/Territory	United States
City	National Harbor
Period	10/1/17 → 10/5/17

All Science Journal Classification (ASJC) codes

General Engineering

Access to Document

10.1149/08008.0259ecst

Cite this

Cantillo, N. M., Li, L., Peng, J., Goenaga, G. A., & Zawodzinski, T. A. (2017). ¹⁹F NMR studies of 3M ionomer adsorption on carbon supports and Pt/C catalysts. In D. J. Jones, F. Buechi, K. E. Swider-Lyons, P. N. Pintauro, H. Uchida, T. J. Schmidt, B. S. Pivovar, H. A. Gasteiger, A. Z. Weber, P. A. Shirvanian, J. M. Fenton, T. F. Fuller, K. Shinohara, K. A. Perry, P. Strasser, C. Coutanceau, S. Mitsushima, R. A. Mantz, S. Narayan, V. Ramani, K. E. Ayers, Y.-T. Kim, ... H. Xu (Eds.), ECS Transactions (8 ed., pp. 259-268). (ECS Transactions; Vol. 80, No. 8). Electrochemical Society Inc.. https://doi.org/10.1149/08008.0259ecst

Cantillo, N. M. ; Li, L. ; Peng, J. et al. / ¹⁹F NMR studies of 3M ionomer adsorption on carbon supports and Pt/C catalysts. ECS Transactions. editor / D. J. Jones ; F. Buechi ; K. E. Swider-Lyons ; P. N. Pintauro ; H. Uchida ; T. J. Schmidt ; B. S. Pivovar ; H. A. Gasteiger ; A. Z. Weber ; P. A. Shirvanian ; J. M. Fenton ; T. F. Fuller ; K. Shinohara ; K. A. Perry ; P. Strasser ; C. Coutanceau ; S. Mitsushima ; R. A. Mantz ; S. Narayan ; V. Ramani ; K. E. Ayers ; Y.-T. Kim ; H. Xu. 8. ed. Electrochemical Society Inc., 2017. pp. 259-268 (ECS Transactions; 8).

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title = "19F NMR studies of 3M ionomer adsorption on carbon supports and Pt/C catalysts",

abstract = "In this study, the interactions between 3M 825 equivalent-weight (EW) ionomer and carbon support or carbon-supported platinum (Pt/C) catalyst particles were studied. The support and catalyst materials (with and without ionomer addition) were analyzed with Brunauer-Emmet-Teller (BET) nitrogen adsorption-desorption. 3M ionomer/carbon/Pt interactions were also explored through differential scanning calorimetry (DSC). Progress toward developing methods for studying polymer adsorption onto supports using 19F Nuclear Magnetic Resonance Spectroscopy (NMR) is also reported. Using these methods, a series of ionomer solutions were analyzed to explore the different interactions between components (Pt/Carbon, and Carbon/ionomer).",

author = "Cantillo, {N. M.} and L. Li and J. Peng and Goenaga, {G. A.} and Zawodzinski, {T. A.}",

note = "Funding Information: NMC gratefully acknowledges the support from a Fulbright Fellowship and from the Office of Naval Research under grant N00014-16-1-2095. Research supported at ORNL by the Fuel Cell Technologies Office, Office of Energy Efficiency and Renewable Energy, U.S. Department of Energy. We would also like to thank 3M for providing the ionomer solution. Publisher Copyright: {\textcopyright} The Electrochemical Society.; Symposium on Polymer Electrolyte Fuel Cells 17, PEFC 2017 - 232nd ECS Meeting ; Conference date: 01-10-2017 Through 05-10-2017",

year = "2017",

doi = "10.1149/08008.0259ecst",

language = "English (US)",

isbn = "9781623324773",

series = "ECS Transactions",

publisher = "Electrochemical Society Inc.",

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pages = "259--268",

editor = "Jones, {D. J.} and F. Buechi and Swider-Lyons, {K. E.} and Pintauro, {P. N.} and H. Uchida and Schmidt, {T. J.} and Pivovar, {B. S.} and Gasteiger, {H. A.} and Weber, {A. Z.} and Shirvanian, {P. A.} and Fenton, {J. M.} and Fuller, {T. F.} and K. Shinohara and Perry, {K. A.} and P. Strasser and C. Coutanceau and S. Mitsushima and Mantz, {R. A.} and S. Narayan and V. Ramani and Ayers, {K. E.} and Y.-T. Kim and H. Xu",

booktitle = "ECS Transactions",

edition = "8",

}

Cantillo, NM, Li, L, Peng, J, Goenaga, GA & Zawodzinski, TA 2017, ¹⁹F NMR studies of 3M ionomer adsorption on carbon supports and Pt/C catalysts. in DJ Jones, F Buechi, KE Swider-Lyons, PN Pintauro, H Uchida, TJ Schmidt, BS Pivovar, HA Gasteiger, AZ Weber, PA Shirvanian, JM Fenton, TF Fuller, K Shinohara, KA Perry, P Strasser, C Coutanceau, S Mitsushima, RA Mantz, S Narayan, V Ramani, KE Ayers, Y-T Kim & H Xu (eds), ECS Transactions. 8 edn, ECS Transactions, no. 8, vol. 80, Electrochemical Society Inc., pp. 259-268, Symposium on Polymer Electrolyte Fuel Cells 17, PEFC 2017 - 232nd ECS Meeting, National Harbor, United States, 10/1/17. https://doi.org/10.1149/08008.0259ecst

¹⁹F NMR studies of 3M ionomer adsorption on carbon supports and Pt/C catalysts. / Cantillo, N. M.; Li, L.; Peng, J. et al.
ECS Transactions. ed. / D. J. Jones; F. Buechi; K. E. Swider-Lyons; P. N. Pintauro; H. Uchida; T. J. Schmidt; B. S. Pivovar; H. A. Gasteiger; A. Z. Weber; P. A. Shirvanian; J. M. Fenton; T. F. Fuller; K. Shinohara; K. A. Perry; P. Strasser; C. Coutanceau; S. Mitsushima; R. A. Mantz; S. Narayan; V. Ramani; K. E. Ayers; Y.-T. Kim; H. Xu. 8. ed. Electrochemical Society Inc., 2017. p. 259-268 (ECS Transactions; Vol. 80, No. 8).

Research output: Chapter in Book/Inform › Conference contribution

TY - GEN

T1 - 19F NMR studies of 3M ionomer adsorption on carbon supports and Pt/C catalysts

AU - Cantillo, N. M.

AU - Li, L.

AU - Peng, J.

AU - Goenaga, G. A.

AU - Zawodzinski, T. A.

N1 - Funding Information: NMC gratefully acknowledges the support from a Fulbright Fellowship and from the Office of Naval Research under grant N00014-16-1-2095. Research supported at ORNL by the Fuel Cell Technologies Office, Office of Energy Efficiency and Renewable Energy, U.S. Department of Energy. We would also like to thank 3M for providing the ionomer solution. Publisher Copyright: © The Electrochemical Society.

PY - 2017

Y1 - 2017

N2 - In this study, the interactions between 3M 825 equivalent-weight (EW) ionomer and carbon support or carbon-supported platinum (Pt/C) catalyst particles were studied. The support and catalyst materials (with and without ionomer addition) were analyzed with Brunauer-Emmet-Teller (BET) nitrogen adsorption-desorption. 3M ionomer/carbon/Pt interactions were also explored through differential scanning calorimetry (DSC). Progress toward developing methods for studying polymer adsorption onto supports using 19F Nuclear Magnetic Resonance Spectroscopy (NMR) is also reported. Using these methods, a series of ionomer solutions were analyzed to explore the different interactions between components (Pt/Carbon, and Carbon/ionomer).

AB - In this study, the interactions between 3M 825 equivalent-weight (EW) ionomer and carbon support or carbon-supported platinum (Pt/C) catalyst particles were studied. The support and catalyst materials (with and without ionomer addition) were analyzed with Brunauer-Emmet-Teller (BET) nitrogen adsorption-desorption. 3M ionomer/carbon/Pt interactions were also explored through differential scanning calorimetry (DSC). Progress toward developing methods for studying polymer adsorption onto supports using 19F Nuclear Magnetic Resonance Spectroscopy (NMR) is also reported. Using these methods, a series of ionomer solutions were analyzed to explore the different interactions between components (Pt/Carbon, and Carbon/ionomer).

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DO - 10.1149/08008.0259ecst

M3 - Conference contribution

AN - SCOPUS:85050032179

SN - 9781623324773

T3 - ECS Transactions

SP - 259

EP - 268

BT - ECS Transactions

A2 - Jones, D. J.

A2 - Buechi, F.

A2 - Swider-Lyons, K. E.

A2 - Pintauro, P. N.

A2 - Uchida, H.

A2 - Schmidt, T. J.

A2 - Pivovar, B. S.

A2 - Gasteiger, H. A.

A2 - Weber, A. Z.

A2 - Shirvanian, P. A.

A2 - Fenton, J. M.

A2 - Fuller, T. F.

A2 - Shinohara, K.

A2 - Perry, K. A.

A2 - Strasser, P.

A2 - Coutanceau, C.

A2 - Mitsushima, S.

A2 - Mantz, R. A.

A2 - Narayan, S.

A2 - Ramani, V.

A2 - Ayers, K. E.

A2 - Kim, Y.-T.

A2 - Xu, H.

PB - Electrochemical Society Inc.

T2 - Symposium on Polymer Electrolyte Fuel Cells 17, PEFC 2017 - 232nd ECS Meeting

Y2 - 1 October 2017 through 5 October 2017

ER -

Cantillo NM, Li L, Peng J, Goenaga GA, Zawodzinski TA. ¹⁹F NMR studies of 3M ionomer adsorption on carbon supports and Pt/C catalysts. In Jones DJ, Buechi F, Swider-Lyons KE, Pintauro PN, Uchida H, Schmidt TJ, Pivovar BS, Gasteiger HA, Weber AZ, Shirvanian PA, Fenton JM, Fuller TF, Shinohara K, Perry KA, Strasser P, Coutanceau C, Mitsushima S, Mantz RA, Narayan S, Ramani V, Ayers KE, Kim YT, Xu H, editors, ECS Transactions. 8 ed. Electrochemical Society Inc. 2017. p. 259-268. (ECS Transactions; 8). doi: 10.1149/08008.0259ecst