Síntesis, caracterización espectroscópica, análisis térmico y estudio por difracción de rayos-X de dos nuevos complejos: L-leucinato de Ni(II) y L-isoleucinato de Ni(II)

Lusbely M. Belandria; Asiloé J. Mora; Pedro J. Vivas; Luis E. Seijas; Gerzon E. Delgado

Síntesis, caracterización espectroscópica, análisis térmico y estudio por difracción de rayos-X de dos nuevos complejos: L-leucinato de Ni(II) y L-isoleucinato de Ni(II)

Translated title of the contribution: Synthesis, spectroscopic characterization, thermal analysis and X-ray diffraction study of two new complexes: Ni(II) L-leucinate and Ni(II) L-isoleucinate

Lusbely M. Belandria
, Asiloé J. Mora
, Pedro J. Vivas
, Luis E. Seijas
, Gerzon E. Delgado

Research output: Contribution to Journal › Research Article › peer-review

Abstract

In this work is presented the synthesis and characterization of the metal complexesL-leucine-Ni (L-Leu-Ni) and L-Isoleucine-Ni (L-Ile-Ni). Both complexes were characterized by FT-IR spectroscopic and TGA-DSC thermal analysis. These analyses indicate that both complexes indicate that both complexes are coordinated to the nickel by the amino and carboxylate groups with two coordination water molecules. Therefore these materials can be called L-leucinate Ni(II) dihydrate and L-isoleucinate Ni(II) dihydrate. The structural analysis using powder X-ray diffraction indi-cates that both complexes crystallize with possible monoclinic space group P2₁.

Translated title of the contribution	Synthesis, spectroscopic characterization, thermal analysis and X-ray diffraction study of two new complexes: Ni(II) L-leucinate and Ni(II) L-isoleucinate
Original language	Spanish
Pages (from-to)	9-14
Number of pages	6
Journal	Avances en Quimica
Volume	17
Issue number	1
State	Published - Jan 1 2022

All Science Journal Classification (ASJC) codes

General Chemistry

Cite this

@article{bc99558317f94732ae325dd01c41236b,

title = "S{\'i}ntesis, caracterizaci{\'o}n espectrosc{\'o}pica, an{\'a}lisis t{\'e}rmico y estudio por difracci{\'o}n de rayos-X de dos nuevos complejos: L-leucinato de Ni(II) y L-isoleucinato de Ni(II)",

abstract = "In this work is presented the synthesis and characterization of the metal complexesL-leucine-Ni (L-Leu-Ni) and L-Isoleucine-Ni (L-Ile-Ni). Both complexes were characterized by FT-IR spectroscopic and TGA-DSC thermal analysis. These analyses indicate that both complexes indicate that both complexes are coordinated to the nickel by the amino and carboxylate groups with two coordination water molecules. Therefore these materials can be called L-leucinate Ni(II) dihydrate and L-isoleucinate Ni(II) dihydrate. The structural analysis using powder X-ray diffraction indi-cates that both complexes crystallize with possible monoclinic space group P21.",

author = "Belandria, \{Lusbely M.\} and Mora, \{Asilo{\'e} J.\} and Vivas, \{Pedro J.\} and Seijas, \{Luis E.\} and Delgado, \{Gerzon E.\}",

year = "2022",

month = jan,

day = "1",

language = "Espa{\~n}ol",

volume = "17",

pages = "9--14",

journal = "Avances en Quimica",

issn = "1856-5301",

publisher = "Universidad de Los Andes",

number = "1",

}

Síntesis, caracterización espectroscópica, análisis térmico y estudio por difracción de rayos-X de dos nuevos complejos: L-leucinato de Ni(II) y L-isoleucinato de Ni(II). / Belandria, Lusbely M.; Mora, Asiloé J.; Vivas, Pedro J. et al.
In: Avances en Quimica, Vol. 17, No. 1, 01.01.2022, p. 9-14.

Research output: Contribution to Journal › Research Article › peer-review

TY - JOUR

T1 - Síntesis, caracterización espectroscópica, análisis térmico y estudio por difracción de rayos-X de dos nuevos complejos

T2 - L-leucinato de Ni(II) y L-isoleucinato de Ni(II)

AU - Belandria, Lusbely M.

AU - Mora, Asiloé J.

AU - Vivas, Pedro J.

AU - Seijas, Luis E.

AU - Delgado, Gerzon E.

PY - 2022/1/1

Y1 - 2022/1/1

N2 - In this work is presented the synthesis and characterization of the metal complexesL-leucine-Ni (L-Leu-Ni) and L-Isoleucine-Ni (L-Ile-Ni). Both complexes were characterized by FT-IR spectroscopic and TGA-DSC thermal analysis. These analyses indicate that both complexes indicate that both complexes are coordinated to the nickel by the amino and carboxylate groups with two coordination water molecules. Therefore these materials can be called L-leucinate Ni(II) dihydrate and L-isoleucinate Ni(II) dihydrate. The structural analysis using powder X-ray diffraction indi-cates that both complexes crystallize with possible monoclinic space group P21.

AB - In this work is presented the synthesis and characterization of the metal complexesL-leucine-Ni (L-Leu-Ni) and L-Isoleucine-Ni (L-Ile-Ni). Both complexes were characterized by FT-IR spectroscopic and TGA-DSC thermal analysis. These analyses indicate that both complexes indicate that both complexes are coordinated to the nickel by the amino and carboxylate groups with two coordination water molecules. Therefore these materials can be called L-leucinate Ni(II) dihydrate and L-isoleucinate Ni(II) dihydrate. The structural analysis using powder X-ray diffraction indi-cates that both complexes crystallize with possible monoclinic space group P21.

UR - https://www.scopus.com/pages/publications/85131200401

UR - https://www.scopus.com/pages/publications/85131200401#tab=citedBy

M3 - Artículo de Investigación

AN - SCOPUS:85131200401

SN - 1856-5301

VL - 17

SP - 9

EP - 14

JO - Avances en Quimica

JF - Avances en Quimica

IS - 1

ER -

Síntesis, caracterización espectroscópica, análisis térmico y estudio por difracción de rayos-X de dos nuevos complejos: L-leucinato de Ni(II) y L-isoleucinato de Ni(II)

Abstract

All Science Journal Classification (ASJC) codes

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