An alternative description of aromaticity in metallabenzenes

Kleyra L. Dávila; Ricardo R. Contreras; Bernardo Fontal; F. Javier Torres; Luis Rincón

doi:10.29356/jmcs.v61i2.256

An alternative description of aromaticity in metallabenzenes

Kleyra L. Dávila, Ricardo R. Contreras, Bernardo Fontal, F. Javier Torres, Luis Rincón

Research output: Contribution to journal › Article › peer-review

2 Scopus citations

Abstract

Experimental and theoretical studies of metallabenzenes have revealed important differences in their aromatic properties when compared with their organic analogs. In this work, an alternative explanation for this unconventional behavior is presented based on the idea that metallabenzenes can be conceived as an intermediate structure between the benzene and the benzenium ion; an idea derived from a critical analysis of the isolobal analogies in metallabenzenes.

Original language	English (US)
Pages (from-to)	97-101
Number of pages	5
Journal	Journal of the Mexican Chemical Society
Volume	61
Issue number	2
DOIs	https://doi.org/10.29356/jmcs.v61i2.256
State	Published - Apr 1 2017
Externally published	Yes

All Science Journal Classification (ASJC) codes

General Chemistry

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abstract = "Experimental and theoretical studies of metallabenzenes have revealed important differences in their aromatic properties when compared with their organic analogs. In this work, an alternative explanation for this unconventional behavior is presented based on the idea that metallabenzenes can be conceived as an intermediate structure between the benzene and the benzenium ion; an idea derived from a critical analysis of the isolobal analogies in metallabenzenes.",

author = "D{\'a}vila, {Kleyra L.} and Contreras, {Ricardo R.} and Bernardo Fontal and Torres, {F. Javier} and Luis Rinc{\'o}n",

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AU - Contreras, Ricardo R.

AU - Fontal, Bernardo

AU - Torres, F. Javier

AU - Rincón, Luis

PY - 2017/4/1

Y1 - 2017/4/1

N2 - Experimental and theoretical studies of metallabenzenes have revealed important differences in their aromatic properties when compared with their organic analogs. In this work, an alternative explanation for this unconventional behavior is presented based on the idea that metallabenzenes can be conceived as an intermediate structure between the benzene and the benzenium ion; an idea derived from a critical analysis of the isolobal analogies in metallabenzenes.

AB - Experimental and theoretical studies of metallabenzenes have revealed important differences in their aromatic properties when compared with their organic analogs. In this work, an alternative explanation for this unconventional behavior is presented based on the idea that metallabenzenes can be conceived as an intermediate structure between the benzene and the benzenium ion; an idea derived from a critical analysis of the isolobal analogies in metallabenzenes.

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An alternative description of aromaticity in metallabenzenes

Abstract

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